研究生: |
江惠聖 |
---|---|
論文名稱: |
Sn-3 Ag-1 Zn 無鉛焊錫軟焊鐵鎳42合金研究 |
指導教授: |
張士欽
|
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2003 |
畢業學年度: | 91 |
語文別: | 中文 |
論文頁數: | 70 |
中文關鍵詞: | 無鉛焊錫 、42合金 |
相關次數: | 點閱:2 下載:0 |
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本研究發現在Sn-3 Ag-1 Zn無鉛銲錫中有兩種不同的析出物。顆粒尺寸較大的析出物,大小約為數個微米。其成份相當接近Ag3Sn。而顆粒尺寸較小的析出物,大小約為100 nm左右。經由TEM/EDX鑑定的結果,部分為Ag3Sn,而部分的析出物則含有大量的鋅。然而,在含有大量鋅的析出物中,其銀和鋅的比例接近1,而錫的含量則不同。因此推測應該是銀鋅化合物(AgZn),而錫(Sn)則來自於基地。為驗證推測,依鑑定出來的錫、銀、鋅比例熔融合金,而此合金的X-Ray diffraction pattern結果證實了推測是正確的。 另外,氯化鋅酒精溶液及氯化亞錫酒精溶液則作為新的助熔劑(Flux)。這兩種助熔劑都能加強銲錫的潤濕能力,且都能在銲錫和基板間形成良好的鍵結。而且試片強度都遠高於利用之前的助焊劑所焊接的試片。而觀察斷面均為密佈的窩穴(Dimples),代表其均為延性破裂。另外,觀察拉伸至不同階段的剝離測試試片則發現破裂皆發生在銲錫中間。
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