研究生: |
巫坤福 |
---|---|
論文名稱: |
RF磁控濺鍍系統成長BSTO/LNO人工超晶格磊晶薄膜之特性研究 Characterization of epitaxial Ba<0.48>Sr<0.52>TiO<3>/LaNiO<3> artificial superlattices prepared by RF magnetron sputtering |
指導教授: | 李志浩 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
原子科學院 - 工程與系統科學系 Department of Engineering and System Science |
論文出版年: | 2005 |
畢業學年度: | 93 |
語文別: | 中文 |
論文頁數: | 100 |
中文關鍵詞: | 人工超晶格薄膜 、射頻磁控濺鍍 、X光分析 、原子力顯微鏡 |
外文關鍵詞: | Superlattice, RF magnetron sputtering, X-ray, AFM, SIMS, BST, STO, LNO |
相關次數: | 點閱:4 下載:0 |
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本實驗成功的利用Radio Frequency磁控濺鍍法製造出磊晶之Ba0.48Sr0.52TiO3/LaNiO3(BST/LNO)人工超晶格薄膜於單晶鈦酸鍶基板與鎳酸鑭底電極薄膜上。藉由X-ray反射率與X-ray繞射以及SIMS之量測觀察超晶格磊晶薄膜微結構之情形。由 X-ray繞射分析顯示在超晶格磊晶薄膜之中的BST層,由c軸的晶格常數會因為界面處的應變而拉長,並造成介電常數之顯著提升,且由a軸晶格常數變化情形,可得薄膜界面產生的應變大小於超晶格薄膜不同之堆疊厚度之關係,並相對於c軸之變化,得知應變提升則有效將c軸晶格拉長;在超晶格磊晶薄膜系統上,space charge、dipolar 與超晶格磊晶薄膜系統上之影響,可藉由不同頻率變化觀察出,由實驗知space charge對於超晶格磊晶薄膜上之界面層多寡有明顯之影響。此外,比對BTO/LNO人工超晶格磊晶薄膜之文獻其結果是一致,所在於界面之應變能夠有效果提升介電性質,且由於Sr元素之加入可以減少介電損失。藉由X光反射率以及X光繞射的量測可發現幾乎固定的界面粗糙度存在於BST與LNO層之間。因此人工超晶格磊晶薄膜具有相同程度將介電常數提升。
Artificial superlattices having ferroelectric Ba0.48Sr0.52TiO3(BST) and conductive LaNiO3(LNO) as modulation length were grown epitaxially on Nb-doped SrTiO3 (001) substrates and LNO bottom-layer prepared by dual-gun Radio Frequency magnetron sputtering system. The formation of superlattice structure was confirmed from the x-ray reflectivity curves and SIMS depth profiles and (0 0 L) Bragg reflection of x-ray. A partial but nearly constant relaxation of in-plane strain in the superlattices was observed. From a macroscopic point of view, the strain in the superlattice structure contributes significantly to the dielectric enhancement. These BTO/LNO and BST/LNO artificial superlattices show a significant enhancement of dielectric constant relative to BTO and BST single layers of the same effective thickness. X-ray reflectivity measurement reveals that the superlattices have about the same interface roughness of BST/LNO. Consequently, nearly the same extent of dielectric enhancement results from the strained BST layer, along with a highly conductive interface zone in the superlattiecs.
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