研究生: |
曹凱揚 Tsao, Kai-Yang |
---|---|
論文名稱: |
多晶/非晶矽屏蔽奈米結構應用於氮化鎵磊晶驗證之強化矽基板 High Strength Si(111) Substrate with Poly-Si/α-Si Sealing Nanotexture for GaN |
指導教授: |
葉哲良
Yeh, Jer-Liang |
口試委員: |
林育芸
Lin, Yu-Yun 侯帝光 Hou, Ti-Kuang 徐文慶 Hsu, Wen-Ching |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 奈米工程與微系統研究所 Institute of NanoEngineering and MicroSystems |
論文出版年: | 2017 |
畢業學年度: | 105 |
語文別: | 中文 |
論文頁數: | 100 |
中文關鍵詞: | 應力強化 、奈米結構 、磊晶 、電子槍蒸鍍系統 |
外文關鍵詞: | stress strengthening, nanotexture, epitaxy, e-gun |
相關次數: | 點閱:2 下載:0 |
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本研究利用電子槍蒸鍍系統(E-gun system)沉積多晶矽(poly-Si)與高密度電漿化學氣相沉積系統(HDP-CVD)沉積非晶矽薄膜製作保護層於本實驗室已證明能強化基板強度之奈米結構上,藉以保護奈米結構並且降低基板翹曲。
利用金屬輔助化學蝕刻(Metal-Assisted Chemical Etching)而蝕刻出之奈米結構能分散矽基板之應力,並提升基板之強度,而此優異的特點能解決矽基板不能承受高功率原件材料氮化鎵(GaN)在磊晶時因晶格不匹配而產生過大應力造成破片的疑慮。但因奈米結構約深4 μm、寬100 nm之高深寬比結構容易附著微粒造成後續製程與機台之汙染,所以CVD (Chemical Vapor Deposition)以一複合矽/二氧化矽材料覆蓋之,其中二氧化矽之晶格常數小於矽而導致超過15 μm甚至50 μm之翹曲,且再後續製程會被清洗液腐蝕而導致附蓋保護層剝落,對正面溫度敏感度高之氮化鎵磊晶薄膜造成直接影響,影響面積超過50%。
本實驗利用E-gun system以物理氣相沉積(Physical Vapor Deposition)之方式沉積多晶矽,其後再以HDP-CVD沉積非晶矽保護薄膜,大幅降低翹曲度最低至4 μm並且不會有氧化物影響磊晶之性質。以此實驗提供一新型基板於氮化鎵磊晶,期望能降低破片率提升產能並精進磊晶品質。
In this study we use E-gun deposition system to deposit poly-Si thin film and HDP-CVD deposited amorphous silicon as a protection layer on the nanotexture which our group has already proved can strengthen the Silicon substrate.
The protection layer can provide that the nanotexture not been damaged and lower the bow of the substrate. We use Metal-Assisted Chemical Etching method to create the nanotexture which disperse the stress on the substrate which can elevate the strength of the wafer to endure the high stress caused by the epitaxy layer of GaN for high power devices. With the nanotexture created by the Metal-Assisted Chemical Etching we can save the wafer from cracking, but due to the high aspect ratio (4 μm high and width for 100 nm) of the nanotexture it may catch particles which is contamination for the later process and facilities. We make a composite material by chemical vapor deposition in order to protect the nanotexture and prevent the contamination problems, but it still exist many flaw such as oxide contamination or over bowing from 15 μm to over 50 μm.
This experiment by using physical vapor deposition by E-gun system and HDP-CVD system, we can derive a poly-Si/a-Si layer which reduce the over bow to 4 μm and will not influence the epitaxy process by oxide. This experiment provide a new strengthening substrate which can lower the cracking rate for a higher productivity.
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