孔洞性金屬有機骨架(Metal−Organic Frameworks, MOF)的動態性與柔性是其主體骨架之一大特徵。本研究藉由溶劑脫附且適當溫度與程序下，來轉換化學鍵並變化了金屬與配位基環境，展現了MOF巨大的結構轉變與功能性變化。
第一部分研究中，提出了一個特殊的MOF晶格重排系統，在溫和條件下，通過鍵連接的變動，可以實現MOF整體晶格的快速重排。該系統在溶劑交換與脫附後約40秒內，結構從低孔隙率與多缺陷的MOF轉變為多孔隙率與高結晶性的異構體，比表面積顯著從725增加至2,749 m2/g。藉由光譜測量結果表示，此MOF晶格重排系統涉及到亞穩中間體生成，其原因為溶劑去除後產生配位不飽和金屬位點，此兩種不同MOF拓撲結構(非晶性-結晶性)之間的轉換，可以通過活化與再浸潤極性溶劑中完成循環以及可逆的結構轉變。
有策略的設計出結合表面超疏水特性、高比表面積與中孔洞，以及優異穩定性的MOF材料是合成化學非常具有挑戰性的研究方向。在第二研究部分中，通過疏水分子(十八烯)選擇性修飾在MOF表面上，且內部結構發生晶格重排的方式，成功的合成出同時擁有超疏水與高比表面積的鋁中孔洞MOF。研究結果顯示，通過『速配接合反應』後修飾方式，將疏水性烷基鏈以共價鍵形式修飾於低孔隙率與多缺陷AlTz-53的表面，隨後，進行溶劑脫附處理，觸發內部結構的晶格重排，最後，內部孔隙率與材料結晶度都有顯著的提升。利用十八烯修飾使AlTz-68表面官能化產生超疏水特性(AlTz-68-C18)，其水滴接觸角為173.6°。AlTz-68-C18也展現出目前文獻有關超疏水議題報導中擁有最大比表面積(2474 m2/g)的材料。另外，在潮濕條件下半年後仍然保持良好的孔隙率以及結構穩定性。此外，AlTz-68-C18與美耐皿海綿可進一步化學鍵結形成複合超疏水材料(AlTz-68-C18@sponge)，也展現出優異的水/油分離效用。

Topological transitions between significantly different phases typically require extreme conditions to collectively break chemical bonds and overcome the stress caused to the original structure by altering its correlated bond environment. In this work, we present a case system that can achieve rapid rearrangement of the whole lattice of a metal–organic framework through a ‘domino’ alteration of the bond connectivity under mild conditions. The system transforms from a disordered amorphous MOF with low porosity to a highly porous and crystalline isomer within 40 seconds upon activation (solvent exchange and desorption), resulting in a significant increase in surface area, from 725 to 2,749 m2/g. Spectroscopic measurements show that this counter-intuitive lattice rearrangement involves a metastable intermediate that results from solvent removal on coordinatively unsaturated metal sites. This amorphous–crystalline switch between two topological distinct MOFs is shown to be reversible over two cycles through activation and re-immersion in polar solvents.
Designing materials that combine surface superhydrophobicity, large surface areas, large and uniform pore sizes as well as excellent stability is a very challenging area for synthetic chemists. In the second system, we demonstrate an effective strategy to construct superhydrophobic mesoporous MOF systems by selectively modifying the external surface of an internal lattice rearranged mesoporous MOF. The surface of defective AlTz-53 with limited porosity is initially modified by hydrophobic alkyl chains through click reactions. Subsequently, the internal framework undergoes lattice rearrangement upon solvent desolvation, leading to a significantly improved internal porosity and material crystallinity. Functionalizing the surface of AlTz-68 with octadecene (AlTz-68-C18) induced superhydrophobicity with a water contact angle of 173.6⁰. AlTz-68-C18 also exhibited the largest BET surface area (2474 m2/g) of all reported superhydrophobic framework materials. A high BET surface area paired with a contact angle of 173.6⁰ yields the superhydrophobic mesoporous AlTz-68-C18 which displays enhanced stability as well as preserved porosity toward moist conditions. Furthermore, the AlTz-68-C18@sponge composite composed of AlTz-68-C18 and sponge exhibits excellent performance towards water/oil separation.

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