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研究生: 陳凌芷
Chen, Ling-Chih
論文名稱: 靜電紡絲複合奈米結晶纖維素奈米纖維直徑變化研究
Diameter Varying Electro-Spun CNC Composite Nano-fiber Study
指導教授: 王威智
Wang, Wei-Chih
口試委員: 陳致真
Chen, Chih-Chen
黃正昇
Huang, Chen-Sheng
學位類別: 碩士
Master
系所名稱: 工學院 - 奈米工程與微系統研究所
Institute of NanoEngineering and MicroSystems
論文出版年: 2018
畢業學年度: 106
語文別: 英文
論文頁數: 97
中文關鍵詞: 電紡絲高分子奈米纖維素結晶聚乙烯醇
外文關鍵詞: elecospinning, polymer, CNC, PVA
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  • 本文介紹了使用電紡絲(ES)設計和製造纖維素奈米結晶(CNC)奈米纖維複合材料。兩個主要研究目標是聚合物複合材料的開發以及圖案化奈米結晶複合 纖維的製造。目前,奈米纖維或複合奈米纖維由一種均勻的被動或活性化高分子 材料製成。目前還沒有關於通過在特殊可控制模式下,利用電磁手段激活電磁特 性的複合奈米纖維的研究。為了實現可控制特別圖案化的奈米纖維,現有的電紡 絲系統被特別修改或增強。在通過靜電紡絲時,在材料製備的後處理過程中摻入 不同功能性材料。這些第二相類的可以包括電介質,感測電和磁的奈米顆粒或聚 合物,全部由纖維素奈米結晶增強機械性質。這項研究的結果是實現對奈米纖維 形態的全面控制並生成可控制特殊形狀複合奈米纖維。


    The thesis presents the design and fabrication of cellulose nanocrystal (CNC) nano-fiber composite using electro-spinning (ES). The two major research goals are the development of CNC polymer composites and the fabrication of patterned CNC composite nanofibers. Currently, nanofibers or composite nanofibers are made of one uniform passive or active material. There is no report of composite nanofibers with electromagnetic properties activated in controlled spatial patterns by electromagnetic means. To achieve the controlled spatial patterned nanofibers, existing ES system is specially modified or augmented. The functional materials are made by incorporating secondary phases either during electrospinning or in post-processing. These secondary phases may include dielectric, electrically and magnetically activated nanoparticles or polymers, all mechanically reinforced by CNCs. The outcome of this research is to achieve full control of nano-fiber morphology and generate controlled spatial patterned composite nanofibers.

    摘要 i Abstract ii Acknowledgements iii Table of Contents iv List of Figures vii List of Tables xiii Chapter 1 Literature research 1 1.1 Cellulose Nanocrystals (CNCs) 1 1.1.1 Overview 1 1.1.2 Background 2 1.1.3 Mechanical and Optical properties 4 1.2 Suspension 6 1.2.1 Background 6 1.2.2 CNC Suspension 8 1.2.3 Poly vinyl alcohol (PVA) 9 1.3 CNC Thin film 10 1.4 Poly(3,4-ethylene dioxythiophene) : polystyrene sulfuric acid 12 1.5 Electro-spinning (ES) 13 1.6 Motivation for spatially patterned CNC composite nanofibers 19 Chapter 2 Design & fabrication of modified CNC and CNC composites 21 2.1 Background 21 2.2 Fabrication 23 2.2.1 CNC TEMPO-oxidation 23 2.2.2 CNC Etherification 25 2.2.3 CNC composites 27 2.3 Material Characterization 29 2.3.1 Copper sulfate modification for CNC TEM microscopic imaging 29 2.3.2 FTIR spectral analysis of CNC 32 Chapter 3 CNC thin film study 44 3.1 CNC thin film 44 3.2 PEDOT/CNC composite 47 Chapter 4 Diameter Varying Nanofiber Electrospinning System 49 4.1 Electrospinning setup 49 4.1.1 Electrospun CNC/PVA nano composite fibers 53 4.1.2 Characterization of CNC/PVA nano composite fibers 57 4.2 External electric field assisted electrospinning process 66 4.3 Magnetic assisted field (MAES) process 70 4.4 Alternating current electric field assisted electrospinning process 72 Chapter 5 Conclusion and Future work 81 5.1 Conclusion 81 5.2 Future work 83 Appendix A- Materials 85 Appendix B- Experimental equipment 86 Reference 87

    [1] Michael Giese, Lina K. Blusch, Mostofa K. Khan, and Mark J. MacLachlan "Functional Materials from Cellulose-Derived Liquid- Crystal Templates", Angewandte International Edition Chemie 2015, 54, 2888–2910
    [2] Wee-Eong TEO, "Beads Formation in Electrospinning, ElectrospinTech”, http://electrospintech.com/beads.html#.WkRw7Rg8V-U
    [3] Youssef Habibi, Lucian A. Lucia, and Orlando J. Rojas, "Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications", Chem. Rev. 2010, 110, 3479–3500
    [4] Roni Marcos dos Santosa, Wilson Pires Flauzino, Netoa Hudson Alves, Silvérioa Douglas Ferreira , Martinsa Noélio Oliveira, Dantasb Daniel Pasquinia "Cellulose nanocrystals from pineapple leaf, a new approach for the reuse of this agro-waste”, Industrial Crops and Products 50 (2013) 707–714
    [5] Rosineide Miranda Leão, Patrícia Câmara Miléo, João M.L.L. Maia, Sandra Maria Luz, "Environmental and technical feasibility of cellulose nanocrystal manufacturing from sugarcane bagasse”, Carbohydrate Polymers 175 (2017) 518–529
    [6] Gilberto Siqueira, Julien Bras and Alain Dufresne, "Cellulosic Bionanocomposites: A Review of Preparation, Properties and Applications”, Polymers 2010, 2, 728-765; doi: 10.3390/polym2040728
    [7] Edward A. Le, Wei-Chih Wang," Improved Processing and Methods for Manufacturing Cellulose Nanocrystal Films", 978-1-4799-6666-0/14 DOI 10.1109/ISOT.2014.89
    [8] “WHAT IS MFC?”,( https://www.exilva.com/About-Exilva/What-is-MFC)
    [9] Johnsy George SN Sabapathi , Food engineering and Packaging Division, Defence Food Research Laboratory, Siddarthanagar, Mysore, Karnataka, india, "Cellulose nanocrystals: synthesis, functional properties, and applications”, Nanotechnology, Science and Applications 2015:8
    [10] Djalal Trache, M. Hazwan Hussin, M. K. Mohamad Haafiz and Vijay Kumar Thakur, "Recent progress in cellulose nanocrystals: sources and production “, Nanoscale, 2017, 9, 1763–1786
    [11] Gopi Krishna Tummala, Ramiro Rojas, and Albert Mihranyan, "Poly(vinyl alcohol) Hydrogels Reinforced with Nanocellulose for Ophthalmic Applications: General Characteristics and Optical Properties" , J. Phys. Chem. B 2016, 120, 13094−13101
    [12] Chen Tian . Shiyu Fu . Lucian A. Lucia, "Magnetic Cu0.5Co0.5Fe2O4 ferrite nanoparticles immobilized in situ on the surfaces of cellulose nanocrystals “, Cellulose (2015) 22:2571–2587 DOI 10.1007/s10570-015-0658-3
    [13] Gopi Krishna Tummala, Thomas Joffre, Viviana R. Lopes, Aneta Liszka, Oleksiy Buznyk, Natalia Ferraz, Cecilia Persson, May Griffith, and Albert Mihranyan, "Hyperelastic Nanocellulose-Reinforced Hydrogel of High Water Content for Ophthalmic Applications " , ACS Biomater. Sci. Eng. 2016, 2, 2072−2079
    [14] E.D. Cranston, D.G. Gray * Department of Chemistry, McGill University, 3420 University Street, Montreal, Que., Canada H3A 2A7, "Formation of cellulose-based electrostatic layer-by-layer films in a magnetic field " , Science and Technology of Advanced Materials 7 (2006) 319–321
    [15] Derek G. Gray and Maren Roman, Department of Chemistry, Pulp and Paper Building, McGill University, Montreal, Quebec H3A 2A7, Canada, Department of Wood Science and Forest Products, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, " Self-Assembly of Cellulose Nanocrystals: Parabolic Focal Conic Films ", Chapter 3, pp 26–32
    [16] D Jayaseelan and P Biji, " Finite element analysis of in-situ alignment of nanoparticles in polymeric nanofibers using magnetic field assisted electrospinning ", Nanosensor Laboratory (NSL), PSG Institute of Advanced Studies, Coimbatore -641 004, India, Mater. Res. Express 2 (2015) 095014
    [17] Hale Oguzlu, Christophe Danumah, Yaman Boluk, “Colloidal behavior of aqueous cellulose nanocrystal suspensions, Current Opinion in Colloid & Interface”, Science 29 (2017) 46–56
    [18] DLVO theory, ( https://en.wikipedia.org/wiki/DLVO_theory)
    [19] Alain, “Introduction to Sol-Gel Processing”, KLUWER ACADEMIC PUBLISHERS
    [20] PAUL J. FLORY,” NETWORK STRUCTURE AND THE ELASTIC PROPERTIES OF VULCANIZED RUBBER”, Chem. Rev., 1944, 35 (1), pp 51–75
    [21] Iler, Ralph K., “The chemistry of silica :silica: solubility, polymerization, colloid and surface properties, and biochemistry” ,New York :Wiley, 1979., xxiv, 866 p.: ill.; 24 cm.
    [22] D.L. SEGAL, “SOL-GEL PROCESSING: ROUTES TO OXIDE CERAMICS USING COLLOIDAL DISPERSIONS OF HYDROUS OXIDES AND ALKOXIDE INTERMEDIATES”, Journal of Non-Crystalline Solids 63 (1984) 183-191
    [23] Siyamak Shahab, Hora A. Almodarresiyeh, Ljudmila Filippovich, Rakesh Kumar, Mahdieh Darroudi, Fatemeh Haji Hajikolaee, “Synthesis of biphenyl derivative and its application as dichroic materials in poly (vinyl alcohol) polarizing films”, Journal of Molecular Structure 1107 (2016) 19e24
    [24] Supachok Tanpichai, Kristiina Oksman, “ Crosslinked poly(vinyl alcohol) composite films with cellulose nanocrystals: Mechanical and thermal properties” J. APPL. POLYM. SCI. 2018, 45710 (1 of 11)
    [25] Darrell H. Reneker, Alexander L. Yarin, “Electrospinning jets and polymer nanofibers”, Polymer 49 (2008) 2387e2425
    [26] Nandana Bhardwaj, Subhas C. Kundu, “Electrospinning: A fascinating fiber fabrication technique”, Biotechnology Advances 28 (2010) 325–347
    [27] Beads Formation in Electrospinning, ElectrospinTech, Author Wee-Eong TEO, ( http://. electrospintech.com/beads.html#.WkRw7Rg8V-U)
    [28] Jan Pelipenko, Julijana Kristl, Biljana Jankovic, Sasˇa Baumgartner, Petra Kocbek University of Ljubljana, Faculty of Pharmacy, Asˇkercˇeva cesta 7, 1000 Ljubljana, Slovenia “The impact of relative humidity during electrospinning on the morphology and mechanical properties of nanofibers”, International Journal of Pharmaceutics 456 (2013) 125–134
    [29] Farah Ejaz Ahmed, Boor Singh Lalia, Raed Hashaikeh, “A review on electrospinning for membrane fabrication: Challenges and applications”, Desalination 356 (2015) 15–30
    [30] Gobind S. Bisht, Giulia Canton, Alireza Mirsepassi, Lawrence Kulinsky, Seajin Oh, Derek Dunn-Rankin, and Marc J. Madou, “ Controlled Continuous Patterning of Polymeric Nanofibers on Three-Dimensional Substrates Using Low-Voltage Near-Field Electrospinning”, Nano Lett. 2011, 11, 1831–1837
    [31] Haider, A. et al., “A comprehensive review summarizing the effect of electrospinning parameters and potential applications of nano- fibers in biomedical and biotechnology”. Arabian Journal of Chemistry (2015), http://dx.doi.org/10.1016/j.arabjc.2015.11.015
    [32] Samuel Eyley and Wim Thielemans, “Surface modification of cellulose nanocrystals”, Nanoscale, 2014, 6, 7764–7779
    [33] Akira Isogai, Tsuguyuki Saito and Hayaka Fukuzumi, “TEMPO-oxidized cellulose nanofibers”, Nanoscale, 2011, 3, 71–85
    [34] 纳米微晶纤维素的制备、改性及其在纸张阻隔涂布中的应用, (http://www.xueshu.com/gncl/201610/28300506.html)
    [35] Ali Sedighi • Majid Montazer • Nahid Hemmatinejad, “Copper nanoparticles on bleached cotton fabric: In situ synthesis and characterization”, DOI 10.1007/s10570-014-0215-5
    [36] MokitChau, ShivanthiE.Sriskandha, DmitryPichugin, HeĺoïseTheŕien-Aubin, DmitroNykypanchuk, GreǵoryChauve, MyriamMet́hot, JeanBouchard, OlegGang, Eugenia Kumacheva, “Ion-Mediated Gelation of Aqueous Suspensions of Cellulose Nanocrystals”, DOI: 10.1021/acs.biomac.5b00701
    [37] IR / FTIR 樣品處理及測定
    [38] Transmittance-Absorbance Conversion Table, ( http://www.finarchemicals.com/pdf/transmittance-absorbance-conversion.pdf)
    [39] Win-IR Pro System Reference Manual, ( http://ch2.ntust.edu.tw/ezfiles/27/1027/attach/83/pta_7914_2247273_75517.pdf)
    [40] HORIBA FT-IR for Windows User’s Manual (Software) CODE : I0042619000C
    [41] Infrared Spectroscopy (http://www.umsl.edu/~orglab/documents/IR/IR2.html)
    [42] Spectroscopy Data Tables
    [43] Mizi Fan, Dasong Dai and Biao Huang (2012). “Fourier Transform Infrared Spectroscopy for Natural Fibres “, Fourier Transform - Materials Analysis, Dr Salih Salih (Ed.), ISBN: 978-953-51-0594-7, InTech, Available from: (http://www.intechopen.com/books/fourier-transform-materials-analysis/fourier-transform-infrared- spectroscopy-for-natural-fibres)
    [44] Infrared Spectroscopy
    [45] N. D. Wanasekara • R. P. O. Santos • C. Douch • E. Frollini • S. J. Eichhorn, “Orientation of cellulose nanocrystals in electrospun polymer fibres “, J Mater Sci (2016) 51:218–227
    [46] H. A. Pohl, K. Pollock Stlllwater, J. S. Crane "Dielectrophoretic Force:, A Comparison of Theory and Experiment”, J. BioL Phys. Volume 6,1978
    [47] E.D. Cranston, D.G. Gray, “Formation of cellulose-based electrostatic layer-by-layer films in a magnetic field”, Science and Technology of Advanced Materials 7 (2006) 319–321
    [48] D Jayaseelan and P Biji, “Finite element analysis of in-situ alignment of nanoparticles in polymeric nanofibers using magnetic field assisted electrospinning”, Mater. Res. Express2(2015)095014
    [49] Matthias M L Arras, Christian Grasl, Helga Bergmeister and Heinrich Schima, “Electrospinning of aligned fibers with adjustable orientation using auxiliary electrodes”, Sci. Technol. Adv. Mater. 13 (2012) 035008 (8pp)
    [50] Muhammad Miftahul Munir, Dian Ahmad Hapidin, and Khairurrijal,” Designing of a High Voltage Power Supply for Electrospinning Apparatus Using a High Voltage Flyback (HVFBT)”, Applied Mechanics and Materials Vol 771 (2015) pp 145-148
    [51] Ji-Huan He,” A Mathematical Model for Preparation by AC-Electrospinning Process”, Nonlinear Sciences and Numerical Simulation 6(3) 243-248, 2005
    [52] Tomáš KALOUS, Pavel POKORNÝ, David LUKÁŠ, Filip SANETRNÍK, ” ELECTRIC WIND PHENOMENA DURING AC COLECTORLESS ELECTROSPINNING”, Nov 5th – 7th 2014, Brno, Czech Republic, EU
    [53] Tao Han, Darrell H. Reneker, Alexander L. Yarin, “Buckling of jets in electrospinning”, Polymer 48 (2007) 6064e6076
    [54] Spin Coating: A Guide to Theory and Techniques, (https://www.ossila.com/pages/spin-coating#advantages-and-disadvantages-of-spin-coating)
    [55] Yunfeng Lu, Rahul Ganguli, Celeste A. Drewien, Mark T. Anderson, C. Jeffrey Brinker, Weilang Gong, Yongxing Guo, Hermes Soyez, Bruce Dunn, Michael H. Huang, Jeffrey I. Zink, “Continuous formation of supported cubic and hexagonal mesoporous films by sol–gel dip-coating “, NATURE | VOL 389
    [56] Xiaodong Wang, Fang Shi, Xiaoxia Gao, Caimei Fan, Wei Huang, Xianshe Feng “A sol–gel dip/spin coating method to prepare titanium oxide films”, Thin Solid Films 548 (2013) 34–39
    [57] Reference: Saturated Vapor Pressure, (http://ddbonline.ddbst.de/AntoineCalculation/AntoineCalculationCGI.exe)
    [58] O. Chiavone-Filho1, E. L. Foletto 2 and L. R. Terron “Representation of phase equilibria and densities for complex systems using a van der Waals volume translated equation of state with a UNIFAC mixing rule”, Ing. Inv., Volume 34, Issue 3, p. 26-30, 2014
    [59] Mark Geoghegan, Georges Hadziioannou, ” Polymer Electronics”, OXFORD MASTER SERIES IN CONDENSED MATTER PHYSICS
    [60] Edward Kang, Gi Seok Jeong, Yoon Young Choi, Kwang Ho Lee, Ali Khademhosseini and Sang-Hoon Lee, “Digitally tunable physicochemical coding of material composition and topography in continuous microfibres “, NATURE MATERIALS | VOL 10 | NOVEMBER 2011
    [61] H. A. Pohl, K. Pollock, J. S. Crane “Dielectrophoretic Force: A Comparison of Theory and Experiment”, Physical Biological Sciences Ltd.
    [62] Tetsuo Kondo, “Hydrogen Bonds in Cellulose and Cellulose Derivatives”, Dumitriu S(Ed.), ISBN 3-540-37102-8, New York, USA

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