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研究生: 陳崇和
論文名稱: 高濃度醇胺於超重力旋轉床吸收CO2之應用
指導教授: 汪上曉
口試委員: 周正晃
王聖潔
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 76
中文關鍵詞: 二氧化碳吸收超重力旋轉床二乙烯三胺二次乙亞胺
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  • 工業革命至今,化石燃料的大量使用,造成二氧化碳濃度增高,使得全球氣候變遷,因此二氧化碳的捕集及封存技術就顯得相當重要。化學吸收法是目前最廣為使用同時也是最有效率的捕獲技術,本研究以高濃度二乙烯三胺(Diethylenetriamine,DETA)與二次乙亞胺(Piperazine,PZ)的混合水溶液,並將醇胺類總濃度控制在8m,於超重力旋轉床(Rotating packed bed,RPB)中,進行二氧化碳吸收實驗。由於PZ於水中溶解度並不高,若吸收劑中的PZ濃度過高,則會使吸收劑容易結晶析出。於是本研究進行各種吸收劑的結晶測試實驗。結果發現同溫度下,20g與200g樣品的結晶狀況不盡相同。但於二氧化碳吸收實驗的整個過程中,皆是在恆溫50℃下進行,因此吸收劑的結晶與否對於實驗操作並不會有太大的影響。
    另外,進行二氧化碳吸收實驗前,本研究先以30wt%的乙醇胺(monoethanolamine,MEA)作為吸收劑,利用氮氣與二氧化碳的個別質量平衡,證明超重力旋轉床整體系統均遵循質量守恆定理。再者,由二氧化碳的吸收實驗結果得知,九種吸收劑的吸收效果差異並不大。最後,本研究以超重力旋轉床的模型,嘗試模擬8mPZ的實驗結果。但整體的模擬效果並不好,其因是8mPZ的基本物理性質在文獻上較不完善。因此需要後續基本物理性質相關數據的量測作業,才可能使模擬結果變的更準確。


    摘要 I 目錄 II 圖目錄 IV 表目錄 V 第一章 緒論 1 一、1 簡介 1 一、2 文獻回顧 2 一、2-1 各類醇胺介紹及其反應機制 2 一、2-2 PZ(piperazine)介紹及其反應機制 5 一、2-3 DETA(diethylenetriamine)介紹及其反應機制 8 一、2-4 超重力旋轉床技術(Higee) 11 一、3 研究動機 12 第二章 實驗設備、藥品與方法 14 二、1 實驗設備 14 二、2 實驗藥品 17 二、3 實驗方法 18 二、3-1 吸收劑溶解度之測試實驗 18 二、3-2 液相滴定分析二氧化碳於MEA中的含量 19 二、3-3 二氧化碳吸收實驗 20 第三章 結果與討論 22 三、1 吸收劑溶解度之測試實驗 22 三、2 質量平衡測試實驗 24 三、3 二氧化碳吸收實驗 26 三、4 超重力旋轉床之模擬 31 第四章 結論 39 符號說明 40 參考文獻 42 附錄-質量平衡測試實驗 45 附錄-二氧化碳吸收實驗 50 8mPZ.................................................................................................................... 50 7mPZ+1mDETA 53 6mPZ+2mDETA 56 5mPZ+3mDETA 59 4mPZ+4mDETA 62 3mPZ+5mDETA 65 2mPZ+6mDETA 68 1mPZ+7mDETA 71 8mDETA ………………………………………………………………………..74

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