簡易檢索 / 詳目顯示

研究生: 蔡秉儒
論文名稱: 固體觸媒生產生質柴油-新式生質柴油反應器
指導教授: 黃世傑
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 51
中文關鍵詞: 生質柴油固體觸媒氣舉式反應器
相關次數: 點閱:1下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 生質柴油為一種兼顧環境保護以及具商業價值的替代性生質能源,而目前商業化的生產,乃是使用均相鹼觸媒進行轉酯化反應,而代轉酯化反應結束,須經過酸鹼中和以及水洗,此舉不利於產品的純化以及分離,並且增加生產成本。若使用非均相之觸媒進行反應,將可簡化生產流程並且使成本降低,使得生質柴油更具有商業化優勢。
    本研究主要使用氣舉式反應器搭配固體鹼觸媒進行轉酯化反應,針對醇油比、觸媒用量及反應溫度等反應參數進行探討,並找出較佳之操作條件。由於氣舉式反應器具有良好的熱量及質量傳導能力,故可增加轉酯化生產生質柴油的產率。由實驗結果得知,在醇油比6、觸媒用量5 wt %、溫度60 ℃、空氣流速31 ml/s、內管管徑48 mm、內管管長300 mm條件下,轉酯化反應於15分鐘內,產率可達最大值98 %。


    1.摘要 2.緒論 3.文獻回顧 4.實驗內容與材料方法 5.結果與討論 6.結論 7.參考文獻

    Agarwal, A. K. and Das, L. M. (2001) Biodiesel development and characterization for use as a fuel in compression ignition engines. Journal of Engineering for Gas Turbines and Power-transactions of the ASME 123(2), 440-447.
    Andreatta, A. E., Casas, L. M., Hegel, P., Bottini, S. B., and Brignole, E. A. (2008) Phase Equilibria in Ternary Mixtures of Methyl Oleate, Glycerol, and Methanol. Ind. Eng. Chem. Res., 47 (15), 5157-5164.
    Canakci, M. and Van Gerpan, J. (1999). Biodiesel production via acid catalysis. Transaction of the ASAE, 42(5), 1203-1210.
    Ebiura, T., Echizen, T., Ishikawa, A., Murai, K., and Baba, T. (2005) Selective transesterification of triolein with methanol to methyl oleate and glycerol using alumina loaded with alkali metal salt as a solid-base catalyst. Applied Catalysis A: General 283, 111–116.
    Encinar JM, Gonzalez JF, Sabio E, and Ramiro MJ. (1999) Preparation and properties of biodiesel from Cynara cardunculus L. oil. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 38(8), 2927-2931.
    Fangrui, M. and Milford, A. H. (1999) Biodiesel production: a review. Bioresource Technology 70, 1-15.
    Freedman, B., Butterfield, R. O., and Pryde, E. H. (1986) Transesterification kinetics of soybean oil. Journal of the American Oil Chemists Society 63(10), 1375-1380.
    Freedman, B., Pryde, E. H., and Mounts, T. L. (1984) Variables affecting the yields of fatty esters from transesterified vegetable oils. Journal of the American Oil Chemists Society 61(10), 1638-1643.
    Furuta, S., Matsuhashi, H., and Arata, K. (2004) Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure. Catalysis Communications 5, 721–723
    Jones, A.G (1985) Liquid circulation in a draft-tube bubble column. Chem. Eng. Sci. 40, 449.
    Khan, A. K. (2002) Research into biodiesel kinetics & catalyst development. University of Queensland, Brisbane, Queensland
    Kim, H. J., Kanga, B. S., Kima, M. J., Park, Y. M., Kimb, D. K., and Lee, J. S. (2004) Transesterification of vegetable oil to biodiesel using heterogeneous base catalyst. Catalysis Today 93–95, 315–320
    Knothe, G., Matheaus, A. C., and Ryan, T. W. (2003) Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel 82(8), 971-975.
    Kusy, P. F. (1982) Transesterification of vegetable oils for fuels, ASAE Publication, Vegetable Oil Fuels, Vol. 4, No. 82, pp.127-137.
    Liu, X., He, H., Wang, Y. and Zhu, S. (2007) Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst. Catalysis Communications 8, 1107-1111.
    Lotero, E., Liu, Y., Lopez, D. E., Suwannakarn, K., Bruce, D. A. and Goodwin, J. G. Jr. (2005) Synthesis of Biodiesel via Acid Catalysis. Industrial & Engineering Chemistry Research, 44(14), 5353-5363.
    Noureddini, H. and Zhu, D. (1997) Kinetics of transesterification of soybean oil. Journal of the American Oil Chemists Society 74(11), 1457-1463.
    Rousseau, I. and BúLock, J. D. (1980) Mixing characteristics of a simple airlift. Biotechnol. Letters, 2, 475-480.
    Sonntag, N. O. V. (1979) Structure and composition of fats and oils. Bailey’s industrial oil and fat products, vol. 1, 4th edition, ed. Swern, D. John Wiley and Sons, New York, p. 99
    Srivastava, A. and Prasad, R. (2000) Triglycerides-based diesel fuels. Renewable and Sustainable Enerty Reviews 4(2), 111-133.
    Vicente, G., Martinez, M., and Aracil, J. (2004) Integrated biodiesel production: a comparison of different homogeneous catalysts systems. Bioresource Technology 92(3), 297-305.
    Weiland, P. (1984) Influence of draft tube diameter on operation behavior of airlift loop reactors. Ger. Chem. Eng. 7,374-385.
    Xie, W. and Huang, X. (2006) Synthesis of biodiesel from soybean oil using heterogeneous KF/ZnO catalyst. Catalysis Letters 107, 53-59.
    Xie, W. and Yang, Z. (2007) Ba-ZnO catalysts for soybean oil transesterification. Catalysis Letters 117(3-4), September ,159-165.
    Yang, Z., and Xie, Z. (2007) Soybean oil transesterification over zinc oxide modified with alkali earth metals. Fuel Processing Technology 88,631-638.
    巫國維,(2007),固體觸媒生產生質柴油之研究,國立清華大學化學工程研究所碩士論文。
    李秉傑,邱宏明,王奕凱合譯 (1988)。非均勻係催化原理應用, 110-113。台北:渤海堂文化事業有限公司。
    洪肇佑,(2000),應用氣舉式反應器進行甲苯光觸媒催化反應之研究,國立清華大學化學工程研究所碩士論文。
    國家標準局,(2007),生質柴油國家標準CNS 15072。
    蔡志源(2008),固體觸媒製造生質柴油之新式轉酯化反應流程,國立清華大學化學工程研究所碩士論文。
    駱呈欣,(2004),內循環氣舉式生物反應器中之局部氣相流力性質與應用於生物降解有機廢氣之行為模式,國立清華大學化學工程研究所博士論文。

    無法下載圖示 全文公開日期 本全文未授權公開 (校內網路)
    全文公開日期 本全文未授權公開 (校外網路)
    全文公開日期 本全文未授權公開 (國家圖書館:臺灣博碩士論文系統)
    QR CODE