研究生: |
彭兆卿 |
---|---|
論文名稱: |
高爐氣燃燒尾氣之二氧化碳吸收溶劑效果評估 Solvent Assessment of CO2 capture from Blast Furnace Vent |
指導教授: | 鄭西顯 |
口試委員: |
汪上曉
遙遠 周宜雄 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2013 |
畢業學年度: | 101 |
語文別: | 中文 |
論文頁數: | 65 |
中文關鍵詞: | CO2捕獲 、化學吸收法 、再生能耗 、氨水 、去酸氨水 |
外文關鍵詞: | MEA, DETA, PZ |
相關次數: | 點閱:2 下載:0 |
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「溫室效應」為工業革命以來全球平均溫度明顯上升之主要原因之一,其中造成溫室效應原因為石化燃料大量使用使得大氣層中CO2濃度明顯增加,為了抑制CO2濃度攀升,「節能減碳」已成為國家能源環境政策發展之重點項目。為此我們於鋼鐵廠及實驗室內各建立一套CO2吸收示範設備,應用各種吸收劑作為相關研究之依據,並提供製程改善方法以達到節能效果。
本研究首先使用吸收劑23 wt% DETA + 20 wt% PZ於鋼鐵廠進行CO2吸收實驗,並針對PZ沉澱問題採取相關停機前及實驗前處理措施並找出最佳操作條件,為現階段最節能之吸收劑;而根據ASPEN模擬結果指出增加再生塔壓力可降低再生能耗,我們針對此製程改善方案以30 wt% MEA設計實驗驗證之。
我們在實驗室內架設小型固定床CO2吸收示範設備,以低濃度氨水捕獲CO2達到吸收率90 %的初步目標;並用此設備探討塔高與CO2吸收率之關係,其實驗結果與ASPEN模擬相當。
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