質傳速率模型已成為填充塔捕獲二氧化碳模擬時一個嚴謹的模組，本研究第一部份則是氨水捕獲二氧化碳之程序進行質傳速率建模，以吸收塔及汽提塔來模擬氨水捕獲二氧化碳的製程，可以發現氨水的進料溫度對於氨氣於吸收塔洩漏的量有明顯的影響。
　　第二部份則探討於氨水捕獲二氧化碳的製程中加入氨水循環的製程來降低吸收塔所排放出來的NH3，並於吸收塔的上端加入水洗塔，且於Mumorah Power station所排出的flue gas 後端加上前置處理塔(pretreatment column)來洗去廢氣中所含的雜質(SOx，NOx…等)，藉由在吸收塔的上端加入水洗塔後可以發現，水洗塔的出口端對於氨氣洩漏的量已控制在1.49~33ppm左右，而水洗氨溶液則藉由水洗塔塔底流至前置處理塔進行氨氣再生以及去除廢氣中雜質，二氧化硫的去除率可高達99.9%，對於氨氣回收使用率可達99.68%，並可將再生的氨氣用於吸收塔捕獲二氧化碳的製程中，藉由此NH3循環系統與CO2捕獲系統的結合可以降低氨洩漏的問題;此外若提高SO2進料濃度時，反而有利於降低氨氣的排放量，因為SO2溶於吸收劑中降低了溶液的pH值，而有助於鹼性氨氣的吸收，因此降低了氨氣出口濃度，而對二氧化碳捕獲系統能耗影響甚小；當提高氨水再生系統循環量時，同樣也有利於降低氨氣的排放量，但對較大的循環量其冷卻和加熱能耗相對有所提升，對二氧化碳捕獲系統能耗則影響不大。
　　第三個部分，則是探討前處理塔後端所排放出來的廢液（含亞硫酸氫銨），藉由分支流將液體中所含有硫的雜質來和臭氧進行反應，其轉化率可達90%以上，並產生高附加價值的硫酸銨。

　　The rate-based model has been a rigorous model to capture carbon dioxide in packed column,so rate-based model for NH3-CO2-SO2-H2O system was developed.
Using absorber and stripper to simulate the process of ammonia to capture carbon dioxide and we found that ammonia-water temperature has an effect on ammonia slip .
　　The second part explores ammonia to capture carbon dioxide in the process of adding NH3 recycle unit to reduce NH3 emissions out of the absorber, and add washing column to the upper of the absorber. Flue gas discharged from Mumorah Power station passing by the pretreatment column to wash away the impurities contained in flue gas such as SOx, NOx ... etc.We combine the pretreatment column and wash column and find that ammonia slip has been controlled at 1.49~33ppm.
Ammonia-water can be heated by flue gas latent heat to regenerate NH3 for recycling,thus saving significant amounts of energy.The proposed process has SO2 removal ratio >99.9% and NH3 reuse efficiencies of 99.68%.
　　Besides,the process is strongly adaptable to different scenarios such as high SO2 level in flue gas and high ammonia-water recycle rate . The high SO2 level is beneficial for reducing NH3 emissions, because the acid gas SO2 dissolve into the solution ,decreasing the pH value and facilitating the absorption of alkaline NH3 gas.But has a little effect on the CO2 capture unit energy comsuptions.The high ammonia-water recycle rate is also beneficial for reducing NH3 emissions,but it will increase the ammonia recovery unit chilling duty and heat duty.It’s also a little effect on the CO2 capture unit energy comsuptions.
　　The third part is to investigate the branch liquid sulfur impurities split from ammonia recovery unit .Because ammonia react with sulfur dioxide producing ammonium bisulfite and ammonium sulfite (NH4HSO3/(NH4)2SO3) which is unstable and low added value.In order to produce high added value ,we add the ozone oxidation process into the system to produce ammonia sulfate((NH4)2SO4).

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