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研究生: 吳宗憲
Wu, Tsung-Tsing
論文名稱: 含多壁奈米碳管之骨水泥複合材料的機械性質研究
Mechanical Properties of Acrylic Bone Cement Composites Reinforced with Multi-walled Carbon Nanotubes
指導教授: 葉孟考
Yeh, Meng-Kao
戴念華
Tai, Nyan-Hwa
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 動力機械工程學系
Department of Power Mechanical Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 96
中文關鍵詞: 奈米碳管骨水泥複合材料溫度
相關次數: 點閱:2下載:0
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  • 摘 要
    奈米材料中的奈米碳管擁有高比強度、高比勁度等優異的物理與機械性質,故常作為補強材。本研究以壓克力骨水泥為研究主題,以骨水泥做為基材,添加不同重量百分比之多壁奈米碳管,探討此複合材料之機械性質。文中也以不同骨水泥藥粉與液態藥劑比例製作含奈米碳管之骨水泥複合材料,探討其對此複合材料機械性質之影響,並找出最適當之藥劑含量。在實驗方面,以單軸壓縮試驗及三點彎曲試驗得到骨水泥複合材料之抗壓、抗彎強度及楊氏模數等機械性質,並量測含奈米碳管之骨水泥複合材料之密度、成型溫度及玻璃轉換溫度。另使用有限單元軟體ANSYS分析骨水泥受壓縮之變形行為,探討分析與實驗結果之機械性質差異。最後以掃描式電子顯微鏡觀察骨水泥複合材料的破壞斷面,討論其破壞機制,結果顯示加入奈米碳管使骨水泥藥粉與藥劑聚合反應不完全,界面強度不佳及碳管團聚,這些因素均造成試片中空孔率增加使得機械性質下降,而改變藥劑含量至適當值可改善奈米碳管骨水泥複合材料之機械性質。奈米碳管之優良熱傳導性質可使骨水泥成型溫度降低,加入奈米碳管可使骨水泥之玻璃轉換溫度及密度提升,且含奈米碳管之骨水泥複合材料與正常成人脊椎骨的骨質密度相近,可臨床應用於人體骨骼填充及修補方面。


    目 錄 摘 要 i Abstract ii 誌 謝 iii 目 錄 iv 圖 表 目 錄 ix 第一章 緒論 1 1.1研究動機 2 1.2文獻回顧 3 1.2.1奈米碳管機械性質量測與電腦模擬 4 1.2.2奈米碳管熱傳性質 5 1.2.3奈米碳管之生物相容性 5 1.2.4奈米複合材料之物理與機械性質 6 1.2.5骨水泥及其複合材料之物理與機械性質 8 1.3研究主題 9 第二章 有限單元與數據分析 10 2.1有限單元分析 10 2.2骨水泥試片之有限單元分析 12 2.3數據分析 13 第三章 實驗步驟 15 3.1實驗儀器 15 3.1.1 CVD系統(圖3.1) 15 3.1.2磁力攪拌機(圖3.2) 15 3.1.3真空烘箱(圖3.3) 16 3.1.4熱壓機(圖3.4) 16 3.1.5電熱偶溫度計(圖3.5) 16 3.1.6紅外線遙測溫度掃描分析儀(圖3.6) 17 3.1.7拋光研磨機(圖3.7) 17 3.1.8電子分析天秤(圖3.8) 17 3.1.9鑽石切割機(圖3.9) 17 3.1.10差式掃描熱分析儀(圖3.10) 18 3.1.11材料試驗機(圖3.11) 18 3.1.12場發射掃描式電子顯微鏡(圖3.12) 18 3.2 CVD製備奈米碳管 18 3.3骨水泥 20 3.4骨水泥製備 20 3.5奈米碳管/骨水泥製備 21 3.6密度量測 22 3.7壓縮試驗 22 3.8三點彎曲試驗 23 3.9增加藥劑含量改變藥粉與藥劑比例 24 3.10差式掃描熱分析儀(differential scanning calorimeter, DSC) (圖3.10) 24 3.11場發射掃描電子顯微鏡觀察 25 第四章 結果與討論 26 4.1骨水泥試片與有限單元法分析 26 4.2量測誤差之探討 27 4.3骨水泥複合材料壓縮測試之結果 28 4.4骨水泥複合材料之三點彎曲測試 30 4.5骨水泥複合材料成型溫度量測 32 4.6骨水泥複合材料DSC測試 32 4.7骨水泥複合材料密度量測 33 4.8改變含奈米碳管之骨水泥複合材料試片製作之加壓條件 35 4.9場發射掃描式電子顯微鏡(FESEM)及結果探討 35 第五章 結論 40 參 考 文 獻 42

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